Product ID:BULLETINE COLOR, 124 MEDIUM ORANGE
MSDS Date:01/31/1994
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CJJLV

T J RONAN PAINT CORP

749 EAST 135TH ST
BRONX, NY 10454
US

Emergency Phone: 800-424-9300

Info Phone: 718-292-1100

Cage: 92086

T J RONAN PAINT CORP

BRONX, NY 10454 US

Telephone: 718-292-1100

Cage: 92086

LEAD

CAS: 7439-92-1

RTECS: OF7525000

ACGIH TLV: 0.15 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CHROMIUM OXIDE (CR4O12); (CHROMIUM)

CAS: 1333-82-0

RTECS: GB6650000

OSHA PEL see Table Z-2

ACGIH TLV: 0.05 MG/M3

2.0 @ 20C.

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

HEAVY STRAIGHT RUN NAPHTHA (PETROLEUM); (MINERAL SPIRITS).

CAS: 64741-41-9

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

PIGMENTS

LEAD CHROMATE

CAS: 7758-97-6

RTECS: GB2975000

ACGIH TLV: 0.012 MG/M3

MOLYBDATE ORANGE

CAS: 12656-85-8

RTECS: QA4660000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: NAUSEA, DIZZINESS,
HEADACHE, VOMITING. SKIN: REPEATED CONTACT MAY CAUSE IRRITATION,
DEFATTING AND DERMATITIS. EYE: CAUSES IRRITATION, REDNESS, TEARING,
BLURRED VISION. INGESTION: C AN CAUSE IRRITATION OF THE DIGESTIVE
TRACT, NAUSEA, VOMITING & DIARRHEA. ASPIRATION INTO THE LUNGS CAN
CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. CHRONIC: LEAD
APPEARS ON THE NAVY LISTING OF OCCUP ATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION FROM APPROPRATE HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD LIST INFORAMTION AND SAFE HANDLING AND
EXPOSURE INFORMATION . (EFTS OF OVE REXP).
Explanation of Carcinogenicity:LEAD CHROMATE: IARC MONOGRAPHS, VOLUME
49, PAGE 49, 1990: GROUP 1. NTP 7TH ANNUAL REPORT ON CARCINOGENS,
1994: KNOWN TO BE CARCINOGENIC. TARGET ORGAN: HUMAN LUNG. MOLYBDATE
ORANGE: IARC MONOGRAPHS, VO LUME 49, PAGE 49, 1990: GROUP 1.
Effects of Overexposure:HLTH HAZ: NOTICE: REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AN D INHALING THIS PRODUCT MAY BE
HARMFUL OR FATAL. PRODUCTS CONTAINING LEAD CHROMATE: (SEE SECTION
2) PROLONGED OR REPEATED EXPOSURE FROM POOR HYGIENE, HOUSEKEEPING
OR HANDLING PRACTICES CAUSES LEAD POI SONING. PROLONGED
OVEREXPOSURE MAY CAUSE DELAYED EFFECTS INVOLVING THE BLOOD,
GASTROINTESTINAL, NERVOUS & REPRODUCTIVE SYSTEMS. LEAD CHROMATE IS
CURRENTLY LISTED AS A SUSPECTED CARCINOGEN.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN OR
RESPIRATORY DISORDERS. ANEMIA.

First Aid:EYE: FLUSH WITH LARGE QUANTITIES OF WATER FOR AT LEAST 15
MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. SKIN: WASH
WITH SOAP AND WATER. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INHALA TION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF
NECESSAARY. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. SEEK MEDICAL ATTENTION IMMEDIATELY.

Flash Point Method:TCC
Flash Point:=41.7C, 107.F
Lower Limits:0.9%
Upper Limits:6.0%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SELF CONTAINED BREATHING
APPARATUS & FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE USED TO
COOL CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. OVEREXPOSURE TO DECOMPOSITION
PRODUCTS MAY CAUSE HEALTH HAZARD. SY MPTOMS MAY NOT BE IMMEDIATELY
APPARENT. OBTAIN MEDICAL ATTENTION.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. COVER WITH
INERT ABSORBENT MATERIAL.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND OPEN
FLAME. KEEP CONTAINERS TIGHTLY CLOSED. STORE AWAY FROM STRONG
OXIDIZING AGENTS IN A COOL DRY PLACE WITH ADEQUATE EXPLOSION PROOF
VENTILATION. AVOID BREATHING VAPOR S. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING.
Other Precautions:DO NOT WELD, HEAT OR DRILL ON OR NEAR CONTAINER; EVEN
EMPTIED CONTAINERS CAN CONTAIN EXPLOSIVE VAPORS. UNIFORMS OR
CLOTHING CONTAINING PAINT RESIDUE SHOULD NOT BE LAUNDERED WITH
HOUSEHOLD GARMENTS. DO NOT TAKE INTERNALLY. OBSERVE LABEL
PRECAUTIONS.

Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS. USE A NIOSH - APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE.
Ventilation:USE EXPLOSION PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR PROTECTIVE CLOTHING AS REQUIRED TO
PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING AND
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
SARA TITLE III: GREEN, #143 PROCESS GREEN, #144 MEDIUM GREEN, #145
PTHALO GREEN, #148 DARK GREEN, #150 BLUE GREEN, #152 LIGHT BLUE,
#153 PTHALO BLUE, #154 PROCESS BLUE, #155 REFLEX BLUE, #156
BRILLIAN T BLUE. PERMANENT RED 2B (MANGANESE) - PIGMENT RED 48:4
CAS# 5280 66-0 AND PIGMENT RED 58:2 (OTHER INFO)

Boiling Pt:>154.4C, 310.F
B.P. Text:310-395F
Vapor Density:HVR/AIR
Spec Gravity:0.924-1.53
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:NEGLIGIBLE

Stability Indicator/Materials to Avoid:YES
ISOLATE FROM OXIDIZERS, HEAT, SPARKS AND OPEN FLAME.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAME.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE AND/OR CARBON
DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR UNDER NORMAL
CONDITIONS.

Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL,
COUNTY, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:DOT: COMBUSTIBLE LIQUID.

SARA Title III Information:SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW
ACT OF 1986 AND OF 40 CFR 372. TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) HAS CREATED NEW
REPORTING REQUIREMENTS FOR COMPANIES THAT HANDLE CERTAIN CHEMICALS
AND CHEMICAL CATEGORIES. THE FOLLOWING IS A LIST OF CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTS OF SARA (4 0 CFR PART 372)
AND THE PRODUCTS THAT CONTAIN THOSE CHEMICALS: COPPER PTHALO BLUE
(COPPER COMPOUND) - PIGMENT BLUE 15:2 CAS# 12239-87- AND PIGMENT
BLUE 14:4 CAS# 147-14-8. % COPPER COMPOUND: 2-3. # 140 LIGHT
GREEN, #142 EMERALD (SUPDAT)
Federal Regulatory Information:OSHA: COMBUSTIBLE LIQUID - CLASS II.
State Regulatory Information:WARNING: THIS PRODUCT AND THE CONTAINER IT
IS IN CONTAIN DETECTABLE AMOUNTS OF ONE OR MORE CHEMICALS KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.